it's always easiest way to ask them directly and get answer directly from them, not some may be/may not be answers.
I made withdraw this morning, and got my money to neteller in a matter of few hrs.
Never had any issue with PS and their withdrawal to get my money in timely maner.
I am in
germany, and what works for me, may not work for you, since i don't know where are you from and what are your country regulations.
They can help you with that.